Figured it out, thanks for the help!
Here is my calculator program if anyone wants to suggest anything to improve it (it doesn't boot up right away, I had to press enter after I executed it to run it, any reason for this?).
Code:
#!/C:Python25/Calc Test.py
print "Welcome to Nolls's Calculator 1.0"
option = 0
while option != 5:
print "1. addition"
print "2. subtraction"
print "3. multiplication"
print "4. division"
print "5. exit"
option = input("Which would you like to do? ")
if option == 1:
a = input("First number ")
print a
b = input("Plus second number ")
print b
print a + b
elif option == 2:
a = input("First number ")
print a
b = input("Minus second number ")
print a - b
elif option == 3:
a = input("First number ")
print a
b = input("Multiplied by second number ")
print b
print a * b
elif option == 4:
a = input("First number ")
print a
b = input("Divided by second number ")
print b
print a / b
elif option == 5:
print "Goodbye!"
exit ()